Preheat the oven to 350°F. Spray three 8-inch cake pans with baking spray. Line the bottoms of the pan with 8-inch parchment paper and spray again.
In a large bowl, mix the flour, cocoa powder, sugar, baking powder, baking soda, and salt. Set aside.
2 ½ cups All-purpose flour, 1 cup Unsweetened cocoa powder, 1 ¾ cups White granulated sugar, 2 ½ teaspoon Baking powder, 1 ½ teaspoon Baking soda, 1 teaspoon Salt
Heat the water on the stove until steaming. In a medium bowl, mix the oil, vanilla, eggs, and buttermilk. Slowly add in the hot water.
¾ cup Oil, 1 teaspoon Pure vanilla extract, 4 Large eggs, 1 cup Buttermilk, 1 cup Hot water
Pour the wet ingredients into the dry. Mix until just combined. The batter will be runny. Separate between the three cake pans.
Bake for 24-28 minutes until a toothpick inserted comes out clean. Let the cakes sit in the hot pan for 10 minutes before transferring to a cooling rack. Cool the cake layers completely before using.