Preheat the oven to 350°F. Spray a 9X9-inch square pan with baking nonstick spray. Place parchment paper on the bottom and spray again. Set aside.
In a large bowl, mix the flour, sugar, cocoa powder, baking powder, baking soda, and salt.
1 ¼ cup All-purpose flour, ¾ cup White granulated sugar, ½ cup Unsweetened cocoa powder, ½ tablespoon Baking powder, ¼ teaspoon Baking soda, ½ teaspoon Salt
Heat the water on the stove top until steaming. In a separate mixing bowl, mix the oil, vanilla, eggs, and buttermilk. Then, very slowly whisk in the hot water.
½ cup Oil, 1 teaspoon Pure vanilla extract, 2 Large eggs, ½ cup Buttermilk, ½ cup Steaming hot water
Pour the wet ingredients into the dry ingredients. Whisk until just combined. There should be minimal lumps in the batter.
Pour the batter into the prepared pan. Bake for 25-30 minutes until a toothpick inserted comes out clean.
Let the cake sit in the hot pan for 10 minutes. Then, transfer to a cooling rack. Cool completely before decorating.