Preheat oven to 350F and spray three 8X2 inch round cake pans with non-stick baking spray. Place 8 inch parchment circle on the bottom and spray again.
In a mixing bowl, mix flour, baking powder, baking soda, salt, cocoa powder and sugar together.
2 ½ cups All-purpose flour, 1 ¾ cups White granulated sugar, 1 cup Dutch process cocoa powder, 1 ½ teaspoon Baking soda, 2 ½ teaspoon Baking powder, 1 teaspoon Salt
In a separate bowl, mix oil, buttermilk, vanilla, and eggs. Heat the hot water on the stove, then very slowly pour the hot water into the wet ingredients. Whisk well while stiring.
1 cup Buttermilk, ¾ cup Oil, 4 Large eggs, 1 teaspoon Pure vanilla extract, 1 cup Hot Water
Pour the wet ingredients into the dry. Whisk together until just combined. Don't over mix.
Evenly spread batter into the three cake pans. Bake for 20-24 minutes. Bake until a toothpick inserted comes out clean.
Let the cakes sit in the hot pan for 10 minutes. Then, transfer to a cooling rack and cool completely.