Preheat the oven to 350℉. Spray three 8-inch cake pans with baking nonstick spray. Line the bottoms with parchment paper circles and spray again.
In a large bowl, sift the flour, cocoa powder, cornstarch, baking powder, baking soda, and salt. Set aside.
2 ¼ cups All-purpose flour, ¼ cup Cornstarch, 1 cup Unsweetened cocoa powder, 2 teaspoon Baking powder, 1 teaspoon Baking soda, 1 teaspoon Salt
In a medium bowl, mix the oil, sugar, vanilla, eggs, and buttermilk. Mix until smooth. Slowly add in the hot water and mix into the batter.
1 cup Oil, 1 ¾ cup White granulated sugar, 1 teaspoon Pure vanilla extract, 4 Large eggs, 1 cup Buttermilk, 1 cup Hot water
Pour the wet ingredients into the dry ingredients and mix using a whisk. Mix until there aren't any flour lumps. It will be a liquidy batter.
Pour the batter into the three cake pans. Bake for 23-26 minutes. Bake until a toothpick inserted comes out clean.
Let the hot cake sit in the pans for 10 minutes. Then, transfer to a cooling rack. Cool completely before decorating.