Preheat the oven to 350℉. Spray a 9-inch springform pan with baking spray. Line the bottom with a parchment paper circle and spray again.
In a large bowl, mix the flour, cornstarch, baking powder, baking soda, salt, and cocoa powder. Set aside.
1 cup All-purpose flour, 2 TBSP Cornstarch, 1 tsp Baking powder, 1/2 tsp Baking soda, 1/2 tsp Salt, 1/2 cup Unsweetened cocoa powder
In a separate bowl, mix the oil, sugar, brown sugar, eggs, vanilla, vinegar, buttermilk, and sour cream until combined using a whisk. Slowly mix in the hot water.
1/2 cup Oil, 1/2 cup White granulated sugar, 1/3 cup Brown sugar, 2 Large eggs, 1 tsp Pure vanilla extract, 1 tsp White vinegar, 1/2 cup Buttermilk, 1/3 cup Sour cream, 1/2 cup Hot water
Pour the wet ingredients into the dry ingredients. Mix until no more lumps remain.
Pour the cake batter into the pan. Bake for 33-36 minutes. Bake until a toothpick inserted comes out clean.
Let the cake sit in the hot pan for 10 minutes before transferring to a cooling rack. Cool completely.