Preheat the oven to 350℉ Spray a 9-inch springform pan with baking spray. Line the bottom with a parchment paper circle. Spray again.
In a medium bowl, sift the flour, cornstarch, cocoa powder, baking powder, baking soda, and salt. Set aside.
1 cup All-purpose flour, 2 TBSP Cornstarch, 1/2 cup Unsweetened cocoa powder, 1 tsp Baking powder, 1/2 tsp Baking soda, 1/2 tsp Salt
In a separate large bowl, Mix the oil, sugar, brown sugar, eggs, vanilla, vinegar, buttermilk, and sour cream.
1/2 cup Oil, 1/2 cup White granulated sugar, 1/3 cup Brown sugar, 2 Large eggs, 1 tsp Pure vanilla extract, 1 tsp White vinegar, 1/2 cup Buttermilk, 1/3 cup Sour cream
Add in the hot water slowly and whisk it in. Add in the dry ingredients and mix until it is a smooth batter.
1/2 cup Hot water
Pour the cake batter into the springform pan. Bake for 30-37 minutes. Bake until a toothpick inserted comes out clean.
Let the cake sit in the hot pan for 10 minutes before transferring to a cooling rack. Cool cake completely before adding the mousse.