Preheat oven to 350°F. Spray a 9X9-inch baking pan with baking nonstick spray. Line the bottom with parchment paper and spray again. Set aside.
In a medium mixing bowl, sift the flour, cornstarch, cocoa powder, baking powder, baking soda, and salt.
1 1/2 cups All-purpose flour, 3/4 cup Dutch process cocoa powder, 1 tsp Baking powder, 1/2 tsp Baking soda, 1/2 tsp Salt, 2 TBSP Cornstarch
In a separate large bowl, mix the oil, sugar, eggs, vanilla, sour cream and buttermilk. Heat water over the stove until steaming. Slowly add and mix into the wet ingredients.
3/4 cup Oil, 1 1/4 cup White granulated sugar, 1 tsp Pure vanilla extract, 3 Large eggs, 1/3 cup Sour cream, 3/4 cup Buttermilk, 3/4 cup Hot water
Add in the dry ingredients and whisk together until smooth and combined.
Pour the cake batter into the cake pan. Bake for 33-38 minutes. The cake is done baking when a toothpick inserted comes out clean.
Let the cake sit in the hot cake pan for 10 minutes before transferring to a cooling rack. Allow to cool completely before decorating.